1254967-12-8

Basic information

• Product Name: C₁₄H₂₀O₄
• Synonyms: C₁₄H₂₀O₄
• CAS NO: 1254967-12-8
• Molecular Weight: 252.31
• Mol File: 1254967-12-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₀O₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₀O₄(1254967-12-8)
• EPA Substance Registry System: C₁₄H₂₀O₄(1254967-12-8)

Safety Data

• Hazardous Substances Data: 1254967-12-8(Hazardous Substances Data)

Upstream product

• 1254967-10-6 3-bromo-2-((2-methoxyethoxy)methoxy)propene 
• 100-52-7 benzaldehyde 

Downstream Products

• 5381-93-1 1-hydroxy-1-phenyl-3-butanone 
• 1254967-14-0 C₁₇H₂₄O₄ 

Relevant articles and documents

Indium-mediated allylation of aldehydes, ketones and sulfonimines with 2-(alkoxy)allyl bromides

2-(Alkoxy)propenyl bromides are readily prepared from 1,3-dibromo-2- propanol in a two-step sequence involving hydroxyl protection and sodium hydride-induced dehydrobromination. Indium-mediated allylation of aldehydes, ketones, and sulfonimines with 2-(alkoxy)propenyl bromides furnishes the corresponding homoallylic alcohols and sulfonamines in good yields. The products can be easily transformed into β-hydroxy ketones and esters, as well as substituted dihydropyrans, and protected β-amino acids. Chiral 2-(alkoxy)propenyl halides, derived from (-)-menthol and d-glucal, furnish diastereomerically enriched products.