1255217-83-4Relevant academic research and scientific papers
Synthesis and Conformational Analysis of Alternately N-Alkylated Aromatic Amide Oligomers
Urushibara, Ko,Masu, Hyuma,Mori, Hirotoshi,Azumaya, Isao,Hirano, Tomoya,Kagechika, Hiroyuki,Tanatani, Aya
, p. 14338 - 14349 (2018)
Alternately N-alkylated aromatic amides such as 1-3 bearing various side chains were designed and synthesized as novel helical foldamers. The CD spectra of oligomers with chiral side chains showed a positive Cotton effect, which indicates that these oligo
Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution
Chabaud, Laurent,Clayden, Jonathan,Helliwell, Madeleine,Page, Abigail,Raftery, James,Vallverdú, Lluís
experimental part, p. 6936 - 6957 (2010/10/02)
A series of oligo-m- and p-benzanilides were made and their conformations in solution were studied by NMR. In most cases, conformational mixtures were observed as soon as three or more monomers were incorporated into the oligomer. Some crystal structures were obtained, which indicated that helical conformations were adopted in the solid state.
