125536-60-9Relevant academic research and scientific papers
The Stereochemistry of the Reaction of α-Silyl Lithium Reagents with Cyclic tert-Butyldimethylsilyl Acyloins.
Prieto, Jose A.,Larson, Gerald L.,Gonzalez, Patricia
, p. 2773 - 2778 (2007/10/02)
The reactions of the tert-butyldimethylsilylated acyloins of five-, six-, and seven-membered rings with the lithium reagents of benzyltrimethylsilane, thiophenoxymethyltrimethylsilane and trimethylsilyl acetonitrile were studied.These reactions favor formation of the substituted (Z) exo methylidene silyl ethers in moderate yields.
