125558-95-4Relevant academic research and scientific papers
Novel cobalt-catalyzed carbonylation of 2-aryl-2-oxazolines
Xu, Hongyu,Jia, Li
, p. 1575 - 1577 (2003)
(Matrix presented) Catalytic ring-expanding carbonylation of 2-aryl-2-oxazolines is reported as a novel method for the synthesis of 4,5-dihydro-1,3-oxazin-6-ones. Various observations suggest the involvement of cobalt radicals as the catalytically active
Synthesis of β-Amino-acid Peptides. Part 3. Preparation of Racemic and Chiral 3-Aminobutyric Acid Derivatives and Peptides Using Dihydrooxazin-6-ones and Conventional Coupling Reagents
Drey, Charles N. C.,Mtetwa, Eli
, p. 1587 - 1592 (2007/10/02)
Peptides of R,S and S-3-aminobutyric acid have been prepared by conventional methods and also by using chiral oxazin-6-ones, the latter method proving to be superior because of the absence of the side-reactions.S-3-Aminobutyric acid derivatives were prepared by Arndt-Eistert homologation.
Selective Hydrogenation of 4,5-Dihydro-1,3-oxazin-6-ones to Carbaldehyde Derivatives; Chemical Differentiation between Acylazetidin-2-ones and the Corresponding Isomeric Oxazin-6-ones
Drey, Charles N. C.,Ridge, Richard J.,Mtetwa, Eli
, p. 378 - 380 (2007/10/02)
Catalytic hydrogenation of optically active and non-active dihydro-oxazin-6-ones unexpectedly led to preferential reduction of the carbonyl group with ring-opening yielding carbaldehyde derivatives.This reaction resolved a structural problem by leading to
