125568-62-9

Upstream product

• 144337-52-0 3,5-bis(methoxymethoxy)-1-<<(tert-butyldimethylsilyl)oxy>methyl>benzene 
• 620177-94-8 methyl 2,6-dibromo-3,5-dihydroxybenzoate 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 79834-15-4 (2-bromo-3,5-bis(methoxymethoxy)phenyl)methanol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 125568-59-4 1-C-<6-<<(tert-butyldimethylsilyl)oxy>methyl>-2,4-bis(methoxymethoxy)phenyl>-2,3,4,6-tetra-O-benzyl-D-glucose 
• 125568-61-8 C₂₄H₂₈O₁₀ 
• 125568-67-4 (2R,3S,4R,5R)-2,3,4,6-Tetrakis-benzyloxy-5-hydroxy-1-(2-hydroxymethyl-4,6-bis-methoxymethoxy-phenyl)-hexan-1-one 
• 1075694-32-4 tert-butyl[{2-(2E-3,7-dimethyl-2,6-octadienyl)-3,5-bis(methoxymethoxy)benzyl}oxy]dimethylsilane 
• 620177-98-2 [3,5-bis(methoxymethoxy)-2-(3-methylbut-2-enyl)phenyl][3,5-dichloro-2-methoxy-6-(methoxymethoxy)-4-methylphenyl]methanone 
• 620177-97-1 [3,5-bis(methoxymethoxy)-2-(3-methylbut-2-enyl)phenyl][3,5-dichloro-2-methoxy-6-(methoxymethoxy)-4-methylphenyl]methanol 
• 620178-00-9 [3,5-dihydroxy-2-(3-methylbut-2-enyl)phenyl](3,5-dichloro-2-hydroxy-6-methoxy-4-methylphenyl)methanone 
• 495412-13-0 2-(3-methylbut-2-enyl)-3,5-bis(methoxymethoxy)benzyl alcohol 
• 495412-14-1 3,5-bis(methoxymethoxy)-2-(3-methylbut-2-enyl)benzaldehyde 

Relevant academic research and scientific papers

A concise synthesis of Pawhuskin A

Pawhuskin A is an isoprenylated stilbene that was isolated from Dalea purpurea and reported to have affinity for the opioid receptor in vitro. It has been synthesized through a convergent sequence that joins a prenylated aldehyde with a geranylated phosphonate in a stereoselective Horner-Wadsworth-Emmons condensation to afford the target E olefin isomer. This synthesis confirms the structure assigned to the natural product and establishes a route that may be used to explore its biological activity and to prepare more active analogues.

Synthetic analogues of the antibiotic pestalone

The first synthetic study towards the natural product pestalone (1) is described culminating in the preparation of selected n-1 analogues. Pestalone is a chlorinated and prenylated benzophenone antibiotic, which is of interest due to a strong activity aga

Synthesis of the papulacandin C-arylglucosyl spiroketal nucleus

The enantiomerically pure tricyclic C-arylglucosyl spiroketal nucleus of papulacandin has been synthesized by reaction of an appropriately protected gluconolactone 4 with a metalated derivative of 5-(hydroxymethyl)resorcinol (5). In model studies, alkylli