125590-91-2

Upstream product

• 125590-04-7 (2E,4E,6E)-(8S,9S,11S)-12-<(tert-Butyldimethylsilyl)oxy>-3,9,11-trimethyl-1-(benzyloxy)-2,4,6-dodecatrien-8-ol 
• 100-39-0 benzyl bromide 
• 101376-74-3 (E)-4-(benzyloxy)-2-methylbut-2-enal 
• 101376-73-2 Methyl (E)-4-(benzyloxy)-2-methyl-2-butenoate 
• 101376-78-7 (8E,10E)-(2R,4R)-12-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-2,4,10-trimethyl-dodeca-8,10-dien-6-yn-5-ol 
• 125496-02-8 ((3E,5E)-7-Benzyloxy-5-methyl-hepta-3,5-dien-1-ynyl)-triisopropyl-silane 
• 101376-77-6 C₁₅H₁₅LiO 
• 101376-76-5 ((2E,4E)-3-Methyl-hepta-2,4-dien-6-ynyloxymethyl)-benzene 
• 60656-87-3 benzyloxyacetoaldehyde 
• 70238-41-4 (E)-4-(benzyloxy)-2-methylbut-2-en-1-ol 
• 101376-79-8 (6E,8E,10E)-(2R,4R)-12-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-2,4,10-trimethyl-dodeca-6,8,10-trien-5-ol 
• 125590-03-6 (2E,4E)-(8S,9S,11S)-12-<(tert-Butyldimethylsilyl)oxy>-3,9,11-trimethyl-1-(benzyloxy)-2,4-dodecadien-6-yn-8-ol 
• 125496-03-9 (2E,4E)-(9S,11S)-12-<(tert-Butyldimethylsilyl)oxy>-3,9,11-trimethyl-1-(benzyloxy)-2,4-dodecadien-6-yn-8-one 

Downstream Products

• 125590-05-8 (6E,8E,10E)-(2S,4S,5S)-5,12-Bis(benzyloxy)-2,4,10-trimethyl-6,8,10-dodecatrien-1-ol 
• 101376-83-4 (2E,8E,10E,12E)-(4R,6R)-7,14-Bis-benzyloxy-2,4,6,12-tetramethyl-tetradeca-2,8,10,12-tetraenoic acid methyl ester 
• 101376-85-6 (2E,8E,10E,12E)-(4R,6R)-7,14-Bis-benzyloxy-2,4,6,12-tetramethyl-tetradeca-2,8,10,12-tetraenal 
• 101376-84-5 (2E,8E,10E,12E)-(4R,6R)-7,14-Bis-benzyloxy-2,4,6,12-tetramethyl-tetradeca-2,8,10,12-tetraen-1-ol 
• 101376-82-3 (6E,8E,10E)-(2R,4R)-5,12-Bis-benzyloxy-2,4,10-trimethyl-dodeca-6,8,10-trienal 
• 101376-81-2 (6E,8E,10E)-(2R,4R)-5,12-Bis-benzyloxy-2,4,10-trimethyl-dodeca-6,8,10-trien-1-ol 
• 125496-04-0 Methyl (3S,4S,4aS,5S,7S,8S,8aS)-8-(Benzyloxy)-4,5,7-trimethyl-3-<(E)-3-(benzyloxy)-1-methyl-1-propenyl>-3,4,4a,5,6,7,8,8a-octahydronaphthalene-4-carboxylate 
• 125590-07-0 (2E,8E,10E,12E)-(4S,6S,7S)-Methyl 7,14-bis(benzyloxy)-2,4,6,12-tetramethyltetradeca-2,8,10,12-tetraenoate 
• 125590-09-2 (2E,8E,10E,12E)-(4S,6S,7S)-7,14-Bis(benzyloxy)-2,4,6,12-tetramethyl-2,8,10,12-tetradecatetraenal 
• 125590-08-1 (2E,8E,10E,12E)-(4S,6S,7S)-7,14-Bis(benzyloxy)-2,4,6,12-tetramethyl-2,8,10,12-tetradecatetraen-1-ol 
• 125590-06-9 (6E,8E,10E)-(2S,4S,5S)-5,12-Bis(benzyloxy)-2,4,10-trimethyl-6,8,10-dodecatrienal 

Relevant academic research and scientific papers

Stereoselective synthesis of a nonracemic hydronaphthalene subunit of Kijanolide

Lewis acid catalyzed Diels - Alder cyclization of the tetraenal 15 affords the endo product, hydronaphthalene 16, with high diastereoselectivity. Nonracemic 15 is prepared by addition of dienyne 5 to resolved (2S,4S)-5-[(tert -butyldimethylsilyl)oxy]-2,4-

A Stereoselective Synthesis of the Hydronaphthalene Substructure of Kijanolide

The synthesis of a hydronaphthalene substructure of the antitumor antibiotic kijanimicin is described in which four of the seven chiral centers are introduced via a diastereoselective intramolecular Diels-Alder cyclization of an all-(E)-2,8,10,12-tetradec