125600-39-7Relevant articles and documents
Solid-state polymerization of monophenylbutadiyne derivatives
Watanabe, Jun-Ichi,Yokoyama, Harumi,Okada, Shuji,Takaragi, Shigeru,Matsuda, Hiro,Nakanishi, Hachiro
, p. 441 - 447 (2011/11/07)
Solid-state polymerization of phenylbutadiyne derivatives with o-nitro, m-nitro or p-nitro group was investigated. All monomers in bulk crystals could be thermally polymerized to become black suggesting formation of extended pi-conjugation system. However, no regular polydiacetylene structures were confirmed by the structural analysis. Nanocrystals of the m-nitro derivative were prepared, and the different polymerization behavior compared with in the bulk crystals was observed. Copyright Taylor & Francis Group, LLC.