1256237-25-8

Basic information

• Product Name: phenethyl 1-(triphenylsilyl)vinyl ketone
• Synonyms: phenethyl 1-(triphenylsilyl)vinyl ketone
• CAS NO: 1256237-25-8
• Molecular Weight: 418.61
• Mol File: 1256237-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenethyl 1-(triphenylsilyl)vinyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: phenethyl 1-(triphenylsilyl)vinyl ketone(1256237-25-8)
• EPA Substance Registry System: phenethyl 1-(triphenylsilyl)vinyl ketone(1256237-25-8)

Safety Data

• Hazardous Substances Data: 1256237-25-8(Hazardous Substances Data)

Upstream product

• 719283-07-5 5-phenyl-2-(triphenylsilyl)pent-1-en-3-ol 

Downstream Products

• 1256237-19-0 (4Z)-4-ethyl-2-methyl-7-phenyl-5-(triphenylsiloxy)-1,4-heptadiene 
• 1256237-21-4 (3Z)-4-benzyl-6-methyl-1-phenyl-3-(triphenylsiloxy)-3-heptene 

Relevant articles and documents

Complete regio- and stereoselective construction of highly substituted silyl enol ethers by three-component coupling

Three components for total control: Trisubstituted silyl enol ethers were prepared by three-component coupling of α-silyl α, β-unsaturated ketones, organocopper reagents, and organic halides with complete regio- and stereoselectivity (see scheme). The reaction proceeded through a 1,3 migration of the silyl group via cyclic silicate intermediates, which controlled the configuration of the silyl enol ethers.