1256258-18-0Relevant academic research and scientific papers
The specific reactivity of 3,4,5-trinitro-1H-pyrazole
Dalinger, Igor L.,Vatsadze, Irina A.,Shkineva, Tatyana K.,Popova, Galina P.,Shevelev, Svyatoslav A.
, p. 253 - 254 (2010)
Nitration of 3,5-dinitropyrazole with HNO3-H2SO4 mixture gives 3,4,5-trinitro-1H-pyrazole, which in reaction with ammonia, amines or thiols under mild conditions undergoes regioselective nucleophilic substitution of the 4-positioned nitro group.
Synthesis and comparison of the reactivity of 3,4,5-1H-trinitropyrazole and Its N-methyl derivative
Dalinger, Igor L.,Vatsadze, Irina A.,Shkineva, Tatyana K.,Popova, Galina P.,Shevelev, Svyatoslav A.,Nelyubina, Yuliya V.
, p. 911 - 924 (2013/08/23)
3,4,5-Trinitro-1H-pyrazole (1) has been obtained via nitration of 3,5-dinitropyrazole with mixture of sulfuric and nitric acids. Compound 1 reacts with excess ammonia and aliphatic amines, in the presence of bases with NH-azoles, phenols, thiols, and trif
Efficient procedure for high-yield synthesis of 4-substituted 3,5-dinitropyrazoles using 4-chloro-3,5-dinitropyrazole
Dalinger, Igor L.,Vatsadze, Irina A.,Shkineva, Tatyana K.,Popova, Galina P.,Shevelev, Svyatoslav A.
experimental part, p. 2058 - 2064 (2012/08/07)
The transformations of readily available 4-chloro-3,5-dinitropyrazole and its N-methylated derivative under the action of anionic S-/O-nucleophiles and neutral N-nucleophiles were studied. Independent of the substrate's charge (anionic, R=H, or neutral, R
