1256267-75-0Relevant academic research and scientific papers
Ferrocene phosphane-carbene ligands in Cu-catalyzed enantioselective 1,4-additions of Grignard reagents to α,β-unsaturated carbonyl compounds
Csizmadiová, Jana,Me?iarová, Mária,Almássy, Ambroz,Horváth, Branislav,?ebesta, Radovan
, p. 47 - 52 (2013/06/27)
Chiral ferrocene phosphane-carbenes are good ligands for the copper-catalyzed 1,4-addition of Grignard reagents to various Michael acceptors. The products were obtained in high enantiomeric purity (up to e.r. = 95:5) and excellent regioselectivity (r.r. =
Enantioselective one-pot conjugate addition of grignard reagents followed by a mannich reaction
Sebesta, Radovan,Bilcik, Filip,Fodran, Peter
supporting information; experimental part, p. 5666 - 5671 (2011/02/28)
Asymmetric addition of Grignard reagents to cyclohexenone, catalyzed by ferrocene diphosphanes, afforded chiral magnesium enolates. These enolates reacted in a one-pot arrangement with N-benzylidenetoluenesulfonamide to give β-amino carbonyl compounds wit
