14674-28-3

Upstream product

• 88-19-7 methyl 2-(aminosulfonyl)benzoate 
• 100-52-7 benzaldehyde 
• 108-88-3 toluene 

Downstream Products

• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 88-19-7 methyl 2-(aminosulfonyl)benzoate 
• 98511-61-6 ⁽¹⁸⁾O-triphenylphosphine oxide 
• 10201-58-8 (E)-1-heptenylbenzene 
• 42817-44-7 (E)-N,N-dimethyl-3-phenylprop-2-en-1-amine 
• 1044499-42-4 (S)-2-cyclohexyl-2,3-dihydroquinazolin-4(1H)-one 
• 1044499-41-3 (R)-2-phenyl-2,3-dihydroquinazolin-4(1H)-one 
• 1256267-75-0 (S,R,R)-N-((2-ethyl-6-oxocyclohexyl)(phenyl)methyl)-4-methylbenzenesulfonamide 
• 1256267-76-1 (R,R,R)-N-((2-ethyl-6-oxocyclohexyl)(phenyl)methyl)-4-methylbenzenesulfonamide 
• 1404439-43-5 C₂₈H₂₃NO₂S 
• 38101-69-8 2-[(E)-styryl]quinoline 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 5422-81-1 (E)-3-phenyl-1-(piperidin-1-yl)-prop-2-en-1-one 

Relevant academic research and scientific papers

Assembly of homoallylamine derivatives through iron-catalyzed three-component sulfonamidoallylation reaction

An efficient FeCl3-catalyzed three-component reaction between aldehydes, sulfonamides and allylsilanes has been achieved, which provides a convenient, atom-economic and green way to construct homoallylamine derivatives. In addition, this reaction exhibits excellent syn stereoselectivity with γ-substituted allylsilanes. A practical three-component cascade process to homoallylamine derivatives is reported, which uses cheap and environmentally benign FeCl3 as catalyst and shows excellent syn stereoselectivity with γ-substituted allylsilanes.

Oxidative imination of toluenes catalyzed by Pd-Au/silica gel under mild reaction conditions

A Pd-Au/SiO2 catalyst was prepared for the oxidative imination of toluenes with up to 99% yields in the absence of dehydrating agents under mild conditions. Nanoparticles with a PdO layer and PdO-Au core may be the active structure for the reaction.

Catalytic asymmetric synthesis of dihydroquinazolinones from imines and 2-aminobenzamides

An unprecedented catalytic asymmetric synthesis of aminal-containing heterocyclic compounds has been developed from imines and tethered nitrogen/nitrogen nucleophiles. In the presence of 10mol% of a commercially available chiral phosphoric acid, a range of aromatic, α,β- unsaturated, and aliphatic imines react with 2-aminobenzamides to give dihydroquinazolinones in good to excellent yields and ee. The enantioselectivity is significantly affected by the imine N-substituent through non-bonding interactions with the chiral phosphoric acid and the 2-aminobenzamide. Copyright

Squaramide-catalyzed enantioselective Friedel-Crafts reaction of indoles with imines

Chiral squaramides are highly enantioselective catalysts for Friedel-Crafts reaction of indoles with N-tosyl imines, affording 3-indolyl methanamine products in 85-96% yields and 84-96% ees. The Royal Society of Chemistry 2010.