125627-30-7Relevant academic research and scientific papers
Investigation of the Chemo- and Stereoselectivity of the Ketene-Claisen Rearrangement
Ernst, Beat,Gonda, Jozef,Jeschke, Rainer,Nubbemeyer, Udo,Oehrlein, Reinhold,Bellus, Daniel
, p. 876 - 891 (1997)
A novel type of ketene-Claisen rearrangement in which the precursor of the rearrangement is generated in situ by reaction of optically active allyl thioethers with dichloroketene is described. A characteristic feature of this rearrangement is the excellen
STEREOSELECTIVE KETENE-CLAISEN REARRANGEMENT OF CHIRAL ALLYLTHIOETHERS
Oehrlein, Reinhold,Jeschke, Rainer,Ernst, Beat,Bellus, Daniel
, p. 3517 - 3520 (2007/10/02)
A new method for the preparation of chiral β-branched, γ,δ-unsaturated thioesters and derivatives is presented, which involves the ketene-Claisen rearrangement of chiral allylthioethers.A novel synthesis of the starting chiral allylthioethers is also desc
