1256363-55-9Relevant academic research and scientific papers
Synthesis of Substituted 6-(1H-1,2,3-Triazol-1-Yl)- 4,7-Dihydro-1,3,5-Dioxazepine
Rudakov,Dubovis,Kulagin,Tsar'Kova,Goloveshkin,Zhilin
, p. 1634 - 1646 (2015/03/05)
A convenient method was developed for the synthesis of 6-(1H-1,2,3-triazol-1-yl)-4,7-dihydro-1,3,5-dioxazepines, using deoxygenation of 1-(5-nitro-1,3-dioxan-5-yl)-1H-1,2,3-triazoles with triethyl phosphite.
Synthesis of heterocyclic geminal nitro azides
Katorov,Rudakov,Zhilin
, p. 2311 - 2317 (2014/05/06)
The oxidative azidation reactions of C-nitro-substituted saturated heterocyclic compounds, viz., the nitro derivatives of oxetane, azetidine, 1,3-dioxane, tetrahydro-1,3-oxazine, and hexahydropyrimidine, were investigated. A novel representatives of the geminal nitro azides were prepared and their physicochemical properties were studied. The process of the formation of the geminal dinitro compounds upon oxidative azidation was analyzed.
