125637-54-9Relevant academic research and scientific papers
NEW CAMPHOR-DERIVED AUXILIARIES IN METHOXYSELENYLATION AND METHOXYBROMINATION WITH OPPOSITE DIASTEREOFACIAL SELECTIVITY. PREPARATION OF β-AMINO ALCOHOL CHIRAL SYNTHONS
Ishizuka, Tadao,Ishibuchi, Seigo,Kunieda, Takehisa
, p. 3449 - 3452 (2007/10/02)
Methoxyselenylation and methoxybromination of chiral 3-acyl-2-oxazolones with PhSeCl/MeOH and Br2/MeC(OMe)3 smoothly proceed to result in highly stereoselective formation of chiral synthons for β-amino alcohols, but with opposite ?-facial selectivity.
