1258071-46-3Relevant academic research and scientific papers
Synthesis and characterization of ruthenium p-cymene complexes bearing bidentate P-N and E-N ligands (E = S, Se) based on 2-aminopyridine
Lackner-Warton, Wolfgang,Tanaka, Shinji,Standfest-Hauser, Christina M.,?ztopcu, ?zgür,Hsieh, Jen-Chieh,Mereiter, Kurt,Kirchner, Karl
, p. 3097 - 3102 (2011/01/08)
The syntheses and characterization of a series of cationic of Ru(II) halfsandwich complexes of the types [Ru(η6-p-cymene) (κ2(P,N)-PN)Cl]+ (PN = N-diphenylphosphino-2- aminopyridine, N-di-iso-propylphosphino-2-aminopyridine, 2-[(2-pyridyl)amino] dibenzo[d,f][1,2,3]dioxaphosphepine, N-(diisopropylphosphino)-2,6- diaminopyridine) and [Ru(η6-p-cymene)(κ2(E,N)- EN)Cl]+ (EN = N-(2-pyridinyl)amino-diphenylphosphine sulfide, N-(2-pyridinyl)amino-diisopropylphosphine sulfide, N-(2-pyridinyl)amino- diphenylphosphine selenide, N-(2-pyridinyl)amino-diisopropylphosphine selenide) is described. Some of these complexes were tested as precatalysts for the transfer hydrogenation of acetophenone to give 1-phenyl ethanol.
