1258408-38-6Relevant articles and documents
Rhodium-catalysed intermolecular alkyne hydroacylation: The enantioselective synthesis of α- and β-substituted ketones by kinetic resolution
Gonzalez-Rodriguez, Carlos,Parsons, Scott R.,Thompson, Amber L.,Willis, Michael C.
supporting information; experimental part, p. 10950 - 10954 (2010/11/05)
Chemical Equation Presented Cleared up! Intermolecular alkyne hydroacylation represents a new addition to the range of transition- metalcatalysed hydroacylation reactions that can be performed in an enantioselective manner. By using a kinetic resolution procedure, both racemic α- and βsubstituted aldehydes can be converted into the corresponding enantiomerically enriched substituted enone products (see scheme).