1258500-83-2Relevant academic research and scientific papers
Oxidative prins-pinacol tandem process mediated by a hypervalent iodine reagent: Scope, limitations, and applications
Beaulieu, Marc-Andre,Guerard, Kimiaka C.,Maertens, Gaetan,Sabot, Cyrille,Canesi, Sylvain
supporting information; experimental part, p. 9460 - 9471 (2012/01/13)
An oxidative Prins-pinacol tandem process mediated by a hypervalent iodine reagent has been developed. This oxidative version of the famous tandem process fits within the concept of "aromatic ring umpolung" and allows the stereoselective transformation of
An oxidative prins-pinacol tandem process and its application to the synthesis of (-)-platensimycin
Beaulieu, Marc-Andre,Sabot, Cyrille,Achache, Nabil,Guerard, Kimiaka C.,Canesi, Sylvain
supporting information; experimental part, p. 11224 - 11228 (2010/11/04)
Center stage: An oxidative Prins-pinacol tandem process mediated by a hypervalent iodine reagent has been accomplished. The strategy allows rapid access to highly functionalized spirocyclic cores (see scheme) present in many natural products. A first application to the formal synthesis of (?)-platensimycin has been achieved.
