1258638-45-7Relevant academic research and scientific papers
A versatile synthesis of αGalCer and its analogues exploiting a cyclic carbonate as phytosphingosine 3,4-diol protecting group
Panza, Luigi,Compostella, Federica,Imperio, Daniela
, p. 50 - 57 (2018/11/26)
A convenient synthetic strategy to αGalCer and some relevant analogues by using a handily protected phytosphingosine is reported here. The conversion of the phytosphingosine amino group to azide and the protection of 3,4-diol as cyclic carbonate group, cl
Synthesis of C -glycoside analogues of α-galactosylceramide via linear allylic C-H oxidation and allyl cyanate to isocyanate rearrangement
Liu, Zheng,Bittman, Robert
, p. 620 - 623 (2012/03/22)
C-Glycoside analogues of α-galactosylceramide were synthesized in which several significant modifications known to promote Th-1 cytokine production were included. The key transformations include C-H oxidation, Sharpless asymmetric epoxidation, olefin cros
