125884-29-9Relevant academic research and scientific papers
Monoacetylation of carbohydrate diols via transesterification with ethyl acetate
Liu, Xuyu,Becker, Bernd,Cooper, Matthew A.
, p. 679 - 683 (2014/05/06)
Monoacetylation of secondary diols in protected monosaccharides was achieved with ethyl acetate as acyl donor and sodium tert-butoxide as a base. The regioseletivity of the reaction varied depending on the substrate. This new method provides a simple, fast, and efficient method to access selectively acetylated carbohydrates that is compatible with acid-sensitive protecting groups. CSIRO 2014.
An easy and versatile approach for the regioselective De-O-benzylation of protected sugars based on the I2/Et3SiH combined system
Pastore, Antonello,Valerio, Silvia,Adinolfi, Matteo,Iadonisi, Alfonso
experimental part, p. 5881 - 5889 (2011/06/24)
The use of cheap and easy to handle reagents, such as I2 and Et3SiH, at low temperature allows the regioselective removal of benzyl protecting groups from highly O-benzylated carbohydrates. The observed regioselectivity is dependent
