1258944-82-9Relevant academic research and scientific papers
Chemoselective catalytic hydrosilylation of nitriles
Gutsulyak, Dmitry V.,Nikonov, Georgii I.
, p. 7553 - 7556 (2010)
Well-behaved: The ruthenium complex [Cp(iPr3P)Ru(NCCH 3)2]+ (Cp=cyclopentadienyl) catalyzes monohydrosilylation of nitriles (see scheme) with unprecedented tolerance of most common functional groups. The catalyst is easily synthesized starting from commercially available compounds, is air-stable, recyclable, and works under solvent-free conditions.
