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1258947-79-3

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1258947-79-3 Usage

General Description

Tris[4-(1H-imidazol-1-yl)-phenyl]amine, also known as TIPA, is a chemical compound with the molecular formula C33H30N6. It is commonly used as a ligand in coordination chemistry and as a building block for the synthesis of coordination polymers and metal-organic frameworks. TIPA has three 4-(1H-imidazol-1-yl)phenyl groups attached to a central amine group, giving it a tris(bidentate) ligand structure. Tris[4-(1H-imidazol-1-yl)-phenyl]amine is highly versatile and has found applications in various fields such as catalysis, material science, and medicinal chemistry. TIPA is known for its ability to form stable complexes with a wide range of metal ions, making it a valuable tool in the development of new functional materials and catalysts.

Check Digit Verification of cas no

The CAS Registry Mumber 1258947-79-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,2,5,8,9,4 and 7 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1258947-79:
(9*1)+(8*2)+(7*5)+(6*8)+(5*9)+(4*4)+(3*7)+(2*7)+(1*9)=213
213 % 10 = 3
So 1258947-79-3 is a valid CAS Registry Number.

1258947-79-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Tipa

1.2 Other means of identification

Product number -
Other names tris[4-(1H-imidazol-1-yl)-phenyl]amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1258947-79-3 SDS

1258947-79-3Downstream Products

1258947-79-3Relevant articles and documents

Highly selective sorption of small hydrocarbons and photocatalytic properties of three metal-organic frameworks based on tris(4-(1H-imidazol-1-yl) phenyl)amine ligand

Fu, Hong-Ru,Kang, Yao,Zhang, Jian

, p. 4209 - 4214 (2014)

By employing a tris(4-(1H-imidazol-1-yl)phenyl)amine (Tipa) ligand, three new metal-organic frameworks, [Zn2(Tipa)(4,4′-bpdc) 1.5(H2O)(NO3)]·2(DMF)·H 2O (1; 4,4′-bpdc = 4,4′-biphenyldicarboxylate, DMF = N,N-dimenthylformamide), [Cd(Tipa)Cl2]·2(DMF)·H 2O (2), and [Co(Tipa)Cl2(H2O)] ·DMF·H2O (3), have been synthesized solvothermally. Compound 1 features a three-dimensional (3D) pillared-layer structure with low band gap and interesting photocatalytic properties. Compound 2 is a 2-fold interpenetrating (3,6)-connected porous framework, and it shows highly selective adsorption of C2H2, CO2, and C 2H4 over CH4. Compound 3 with honeycomb-like layers exhibits unusual 2D + 2D- 3D polycatenation (2D = two-dimensional). The luminescent properties for these compounds were also investigated.

A new tridentate fluorescent-colorimetric chemosensor for copper(II) ion

Zhao, Zhi-Xiang,Hu, Ze-Liang,Zhang, Xian-Tao,Liu, Qing-Xiang

, (2019)

A new tri-imidazolium salt, tris(4-(3-(2-((8-hydroxy-9,10-dioxo-9′,10′-dihydroanthracen-1-yl)oxy)ethyl)-1H-imidazole-3′-ium-1′-yl)phenyl)amine hexafluorophosphate was prepared and characterized. Particularly, the recognition performance of the tri-imidazo

A 3D luminescent metal-organic framework constructed from Cu 4I4 cubane clusters and triangular imidazole ligand

Liu, Shan-Shan,Yuan, Shuai,Hu, Tuo-Ping,Sun, Di

, p. 2030 - 2034 (2014)

The solvothermal reaction between cuprous iodide and the rigid triangular imidazole ligand in mixed N,N'-dimethylacetamide (DMA)-acetonitrile solvent leads to the isolation of the 3D metal-organic framework [(Cu4I 4)3(TIPA)4]·7DMA (1) [TIPA = tri(4-imidazolylphenyl) amine], which was characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. Topologically, the structure of 1 is an unprecedented 3,3,4,4-connected net with a point symbol of {4.8.10}2{4.82}2{4 2.82.102}2{84.12 2}. Compound 1 exhibits orange-red photoluminescence with an emission maximum at 622 nm at room temperature. Copyright

An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand

Wu, Hua,Liu, Hai-Yan,Liu, Ying-Ying,Yang, Jin,Liu, Bo,Ma, Jian-Fang

, p. 1818 - 1820 (2011)

An unprecedented 2D → 3D metal-organic polyrotaxane framework, based on a new star-like tri(4-imidazolylphenyl)amine ligand, has been synthesized and characterized, which represents the first example of 2D → 3D polyrotaxane entangled in a parallel fashion.

Chiral and porous coordination polymers based on an N-centered triangular rigid ligand

Yao, Xiao-Qiang,Cao, Da-Peng,Hu, Jin-Song,Li, Yi-Zhi,Guo, Zi-Jian,Zheng, He-Gen

, p. 231 - 239 (2011)

Four cadmium and cobalt coordination polymers with unique structures and topologies have been successfully synthesized under solvothermal conditions by employing an elongated triangular rigid N-containing ligand tris(4-(1H-imidazol- 1-yl)phenyl)amine (TIPA) and 5-hydroxyisophthalic acid (5-OH-H2bdc) as anion coligand. Compounds 1-4 were characterized by single crystal X-ray structure analyses, thermogravimetric analyses, SHG, and photoluminescent measurements. Compound 1 crystallizes in the chiral space group C2 (No. 5) and features a 2D → 3D parallel/parallel inclined polycatenated framework. Compound 2 crystallizes in trigonal symmetry with a high-symmetry space group R3 and features a 2D porous noninterpenetrating coordination network. Compound 3 crystallizes in the monoclinic space group P21/n and shows a 2D → 3D parallel/parallel polycatenation framework, and compound 4 crystallizes in the orthorhombic chiral space group P212 121 (No. 19) and shows a very rarely 3D + 3D heterogeneous 2-fold interpenetration framework built from (3,5)-connected (4 2·65·83)(42·6) AFUQOH nets and (3,5)-connected (63)(69·8) gra nets.

Imidazole derivative polyaromatic cartankylate iron complex as well as preparation method and application thereof

-

Paragraph 0067-0070; 0091-0094; 0111-0114, (2020/12/08)

The invention discloses an imidazole derivative polyaromatic cartankylate iron complex, the chemical name of which is monohydrate 1, 2-tri (4-imidazolylphenyl) amino-4, 4 ', 4' '-(1, 3, 5-triazine-2,4, 6-triyl) iron tribenzoate. A preparation method comprises the following steps: in a mixed solvent of water and an organic solvent, carrying out a hydrothermal reaction on tris (4-imidazolyl phenyl)amine, 4, 4 ', 4' '-(1, 3, 5-triazine-2, 4, 6-triyl) tris (trimellitic acid) and a Fe (II) source, cooling and crystallizing to obtain the Fe (II)-tris (4-imidazolyl phenyl) amine. The complex can beused as a positive electrode material of a supercapacitor and has an application prospect in the field of electrochemical energy storage. The material and a carbon-containing iron oxide/iron nitridemixture obtained by calcining the material at high temperature can be respectively used as a positive electrode material and a negative electrode material of a supercapacitor, and the assembled asymmetric supercapacitor has the characteristics of high capacitance, capability of being recycled for multiple times and relatively low resistance.

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