125992-55-4Relevant academic research and scientific papers
Lipase mediated enantiomer and diastereomer separation of 2,2′-[1,2- and 1,3-phenylenebis(oxy)]dicyclohexanols
Toke, Eniko R.,Kolonits, Pal,Novak, Lajos,Poppe, Laszlo
, p. 2377 - 2385 (2007/10/03)
Separation of diastereomeric and enantiomeric mixtures of 2,2′-[1,2- and 1,3-phenylenebis(oxy)]dicyclohexanols rac-3a and meso-3a, and rac-3b and meso-3b-resulting from the reactions of pyrocatechol 1a and resorcinol 1b with cyclohexene oxide 2-were perfo
A Convenient Enantioselective Synthesis of trans-2-Aryloxycyclohexan-1-ols Using Pig Liver Acetone Powder (PLAP) as Biocatalyst
Basavaiah, Deevi,Krishna, Peddinti Rama,Bharathi, Tirumala K.
, p. 439 - 454 (2007/10/02)
Pig liver acetone powder (PLAP) has been used as a biocatalyst for enantioselective hydrolysis of racemic trans-1-acetoxy-2-aryloxycyclohexanes to produce the resulting (R,R)-2-aryloxycyclohexan-1-ols upto >99percent enantiomeric purities. (R,R)-Selectivity in this hydrolysis of racemic trans-2-aryloxycyclohexyl acetates was explained on the basis of Jones' three dimensional active site-model.
Enzymic Preparation of Enantiomerically Pure Cyclohexanols: Ester Synthesis by Irreversible Acyl Transfer
Laumen, Kurt,Seemayer, Robert,Schneider, Manfred P.
, p. 49 - 51 (2007/10/02)
Enantiomerically pure cyclohexanols are prepared enzymically via irreversible acyl transfer; they are valuable substitutes for 8-phenylmenthols and are potentially useful as chiral auxiliaries.
