126001-13-6

Basic information

• Product Name: 1-(p-nitrobenzyl)-6-nitro-1H-indazole
• CAS NO: 126001-13-6
• Molecular Weight: 298.258
• Mol File: 126001-13-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(p-nitrobenzyl)-6-nitro-1H-indazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-nitrobenzyl)-6-nitro-1H-indazole(126001-13-6)
• EPA Substance Registry System: 1-(p-nitrobenzyl)-6-nitro-1H-indazole(126001-13-6)

Safety Data

• Hazardous Substances Data: 126001-13-6(Hazardous Substances Data)

Upstream product

• 100-14-1 4-nitrobenzyl chloride 
• 7597-18-4 6-nitroindazole 

Relevant articles and documents

Radical-Nucleophilic Substitution (SRN1) Reactions. Part 6. N-Anions of Diazoles in SRN1 and Oxidative Additions

The anions of imidazole, benzimidazole, 5(6)-nitrobenzimidazole, and 5(and 6)-nitro-1H- and -2H-indazoles have been shown to undergo oxidative addition to the anion of 2-nitropropane (using potassium ferricyanide and sodium persulphate), and SRN1 reactions with Me2C(X)NO2 (X = Cl, Br, and NO2) to yield the corresponding 1-(1-methyl-1-nitroethyl) derivatives.The anions of 5(6)-nitrobenzimidazole and 5(6)-nitro-1H- and -2H-indazoles underwent reaction with p-nitrobenzyl chloride by a SRN1 and/or SN2 mechanism to yield the corresponding 1-(p-nitrobenzyl) derivatives.The ambident anions of 5- and 6-nitrobenzimidazole, 5-nitro-1H- and -2H-indazoles, and 6-nitro-1H- and -2H-indazoles gave ca. 50:50 mixtures of the N-1 alkylation products resulting from respective pairs of ambident anions.The 1-(1-methyl-1-nitroethyl) derivatives of benzimidazole and 5- and 6-nitro-1H-indazole underwent further substitution of the aliphatic nitro group with the respective diazole to yield 2,2-di(benzimidazol-1-yl)-, 2,2-dipropanes.