1260071-20-2

Upstream product

• 122-51-0 orthoformic acid triethyl ester 
• 5720-07-0 4-methoxyphenylboronic acid 
• 17200-29-2 5-chloro-benzoxazole 

Downstream Products

• 1260071-13-3 5-(4-methoxy-phenyl)-benzoxazole-2-carboxylic acid hexyl ester 
• 1422200-32-5 5-(4-methoxyphenyl)-2-(2,3,4,5-tetrafluoro-6-(pyridin-2-yl)phenyl)benzoxazole 
• 1602493-35-5 C₂₁H₁₅NO₃ 
• 1404370-50-8 5-(4-methoxyphenyl)-N,N-dimethylbenzo[d]oxazol-2-amine 

Relevant academic research and scientific papers

Cu-Catalyzed Direct C-P Bond Formation through Dehydrogenative Cross-Coupling Reactions between Azoles and Dialkyl Phosphites

A direct dehydrogenative cross-coupling of azoles [C(sp2)-H] with dialkyl phosphites [P(O)-H] to access 2-phosphonated azoles using Cu(I)/Cu(II) as catalyst and K2S2O8/di-tert-butylperoxide as oxidant has been achieved. A remarkable advantage over reported procedures includes that oxazoles, imidazoles, benz(ox/othi/imid)azoles, and indole are found to react under optimized reaction conditions to provide corresponding adducts in high yields. The mechanistic insight of cross-coupling was obtained by deuterium kinetic isotope effect studies.

Palladium-catalyzed coupling of polyfluorinated arenes with heteroarenes via C-F/C-H activation

The first palladium-catalyzed coupling of 2-pyridyl-polyfluoroarenes and benzoxazole, thiazole, benzothiazole, benzoimidazole, oxazole or oxadiazole via a concurrent C-F/C-H activation is described. Initial mechanistic studies showed that C-F activation o

Copper-catalyzed direct carboxylation of C-H bonds with carbon dioxide

Cooking with gas: Copper complexes serve as excellent catalysts for the direct carboxylation of aromatic heterocyclic C-H bonds with CO2, thereby offering an economical and environmentally benign process for the synthesis of heterocyclic carbox