1260083-83-7

Upstream product

• 1260083-82-6 C₁₇H₂₆O₃ 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 132340-20-6 (S,E)-1-(benzyloxy)pent-3-en-2-ol 
• 1313708-38-1 (2R,3E)-2-[5-(benzyloxy)pent-3-en-2-yl]-4-(methoxymethoxy)-5-methylphenol 
• 1360594-03-1 (4R)-4-[2-(tert-butyldimethylsilyloxy)-5-(methoxymethoxy)-4-methylphenyl]pentan-1-ol 
• 183623-25-8 C₁₂H₁₆O₂ 
• 1313708-40-5 4-(methoxymethoxy)-3-methylphenol 
• 3043-64-9 1-phenyl-5-(propane-2-sulfonyl)-pr1H-tetrazole 
• 1360594-04-2 C₂₀H₃₄O₄Si 

Downstream Products

• 1360594-07-5 C₂₃H₄₂O₅Si 

Relevant academic research and scientific papers

Highly efficient, enantiocontrolled total syntheses of (+)-heliannuol D and (-)-helibisabonol A

Enantiocontrolled total syntheses of (+)-heliannuol D (1) and (-)-helibisabonol A (2) have been accomplished efficiently from a common intermediate 9, derived from the optically pure aryl allyl ether 7 via a chirality transfer through a Lewis acid-mediate

Enantioselective total synthesis of heliespirone B

The first enantiocontrolled total synthesis of heliespirone B has been accomplished employing a biomimetic intramolecular oxy-Michael reaction followed by the regio- and diastereoselective reduction of the carbonyl function as key steps.

An efficient total synthesis of (+)-heliannuol D

An efficient total synthesis of (+)-heliannuol D was accomplished in 14 steps and in 12% overall yield by employing a diastereoselective conjugate addition reaction to create a tertiary benzylic stereogenic center and simple assembly of the functionalized oxepane framework by an efficient one-pot transformation procedure as the key steps.