1260428-45-2Relevant academic research and scientific papers
Morpholinosulfur trifluoride (morph-DAST)-mediated rearrangement in the fluorination of cyclic α,α-dialkoxy ketones toward 1,2-dialkoxy-1,2-difluorinated compounds
Surmont, Riccardo,Verniest, Guido,De Groot, Alex,Thuring, Jan Willem,De Kimpe, Norbert
, p. 2751 - 2756 (2010)
The deoxofluorination of cyclic α,α-dialkoxy ketones with morpholinosulfur trifluoride (Morph-DAST) resulted in 1,2-dialkoxy-1,2- difluorinated carbo- and heterocyclic compounds. The reaction proceeds via a 1,2-alkoxy migration leading to mixtures of cis-
