126083-90-7

Basic information

• Product Name: [NbCl₃(1,2-dimethoxyethane)(PhC₂Et)]
• CAS NO: 126083-90-7
• Molecular Weight: 419.577
• Mol File: 126083-90-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [NbCl₃(1,2-dimethoxyethane)(PhC₂Et)](CAS DataBase Reference)
• NIST Chemistry Reference: [NbCl₃(1,2-dimethoxyethane)(PhC₂Et)](126083-90-7)
• EPA Substance Registry System: [NbCl₃(1,2-dimethoxyethane)(PhC₂Et)](126083-90-7)

Safety Data

• Hazardous Substances Data: 126083-90-7(Hazardous Substances Data)

Upstream product

• 110615-13-9 niobium(III) chloride dimethoxyethane 
• 622-76-4 1-phenyl-1-butyne 

Downstream Products

• 197085-21-5 NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)(C₆H₅CCC₂H₅) 
• 197085-11-3 [NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)]2 

Relevant articles and documents

Synthesis and characterization of trihaloniobium alkyne complexes

Neutral, monomeric trihaloniobium alkyne complexes of the general formula LnX3Nb(RC≡CR′) (X = Cl, Br L = dimethoxyethane (DME, n = 1); X = Cl, L = tetrahydrofuran (THF, n = 2)) are conveniently prepared from the reaction of NbX3(DME) with alkynes. An X-ray crystal structure of (THF)2Cl3Nb-(PhC≡CSi(t-Bu)Me2) was obtained and indicates that the alkyne unit is bound to niobium in a highly symmetric fashion with identical niobium-carbon distances (2.067 (2) ?). The synthesis of NbBr3(DME) is reported.