197085-11-3

Basic information

• Product Name: [NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)]2
• CAS NO: 197085-11-3
• Molecular Weight: 1173.41
• Mol File: 197085-11-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)]2(197085-11-3)
• EPA Substance Registry System: [NbCl₃(C₃H₂NSC(CHP(C₆H₅)3)O)]2(197085-11-3)

Safety Data

• Hazardous Substances Data: 197085-11-3(Hazardous Substances Data)

Upstream product

• 126083-90-7 [NbCl₃(1,2-dimethoxyethane)(PhC₂Et)] 
• 136029-15-7 1-(thiazol-2-yl)-2-(triphenyl-λ ⁵-phosphanylidene)ethan-1-one 
• 126083-92-9 NbCl₃(1,2-dimethoxyethane)(MeC_.tplbond.CMe) 

Relevant articles and documents

Phosphorus ylide niobium complexes; synthesis and characterization of the first α-keto ylide complexes,[{NbCl3(ylide-O,N)}2] and [NbCl3(ylide-O,N)n(RC≡CR′)] (ylide = [{2-thiazolylcarbonyl}methylene]triphenylphosphorane

Reactions of [{NbCl3(dme)n}] or [NbCl3(dme)(RC≡CR′)] with a heterocycle containing α-keto stabilized phosphorus ylide, 2-TCMP = [{2-thiazolylcarbonyl}methylene]triphenylphosphorane, allowed the synthesis of the first α-keto ylide niobium complexes, [{NbCl3(2-TCMP)}2] and [NbCl3(2-TCMP)(RC≡CR′)] respectively. The new complexes were spectroscopically characterized and the X-ray molecular structure for one of them was also determined.