126117-45-1Relevant articles and documents
Triarylantimony Dicaroxylates Ar3Sb[OC(O)R]2 (Ar = Ph, p-Tol; R = 2-C4H3O, 3-C5H4N): Synthesis and Structure
Sharutin,Sharutina,Pakusina,Platonova,Zhidkov,Pushilin,Gerasimenko
, p. 694 - 702 (2003)
Bis(2-furoinate)triphenyl- and tri-p-tolylantimony and bis(3-niacinate) triphenylanitmony were synthesized by reacting triarylantimony (Ar 3Sb; Ar = Ph, p-Tol) with 2-furancarboxylic and 3-pyridinecarboxylic acids in the presence of hydrogen peroxide. According to X-ray diffraction data, Sb atoms have trigonal bipyramidal coordination polyhedra. The Sb-O distances are 2.117(4), 2.137(4) A; 2.136(2), 2.158(2) A, and 2.112(1), 2.101(2) A, the Sb...O distances are 2.866(4), 2.798(4) A; 2.816(2), 2.774(2) A, and 3.054(2), 3.168(2) A, respectively.