126188-00-9

Basic information

• Product Name: {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}BF₄
• CAS NO: 126188-00-9
• Molecular Weight: 924.127
• Mol File: 126188-00-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}BF₄(126188-00-9)
• EPA Substance Registry System: {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}BF₄(126188-00-9)

Safety Data

• Hazardous Substances Data: 126188-00-9(Hazardous Substances Data)

Upstream product

• 14104-20-2 silver tetrafluoroborate 
• 126251-92-1 {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}Cl 

Downstream Products

• 143337-09-1 (C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)4⁽²⁺⁾*Cl^(1-)*BF₄^(1-)={(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)4}Cl(BF₄) 

Relevant articles and documents

Synthesis of New Cationic BINAP-Ruthenium(II) Complexes and their Use in Asymmetric Hydrogenation

Reaction of 2 (1) and (S)-BINAP gives cationic BINAP-ruthenium complexes of the formula Y (2) (X = Cl, Br, and I; Y = Cl, Br, I, BF4, and BPh4; arene = C6H6 and p-MeC6H4CHMe2) which are efficient catalyst precursors for enantioselective hydrogenation of various prochiral alkenic and ketonic substrates ; a crystal structure of (2) (with X = Cl, Y = BF4) was obtained.