126188-98-5Relevant academic research and scientific papers
The 'valence tautomers' of o-iodosobenzoic acid: The case of 4-pentyl-2-iodosobenzoic acid
Moss, Robert A.,Vijayaraghavan, Saketh,Emge
, p. 1559 - 1560 (2007/10/03)
Contrary to a previous report, only the closed (iodoxolone) form of 4-pentyl-2-iodosobenzoic acid (3a) can be isolated; the previously assigned open (iodoso) form (3b) is actually 4-pentanoyl-2-iodobenzoic acid.
Synthesis of 4-Alkyl-2-iodosobenzoic Acids: Potent Catalysts for the Hydrolysis of Phosphorous Esters
Panetta, Charles A.,Garlick, Stephanie M.,Durst, H. Dupont,Longo, Frederick R.,Ward, J. Richard
, p. 5202 - 5205 (2007/10/02)
The syntheses of five new 4-alkyl-2-iodosobenzoic acids (3) are described.The iodine atom was introduced by ortho-directed lithiation of 4-alkylbenzyl alcohols followed by treatment with I2.The catalytic effectiveness of each of the products in the hydrolysis of 4-nitrophenyl diphenyl phosphate in microemulsions was studied.The 4-methyl- and 4-ethyl-substituted products were each found to be significantly better catalysts than the standard nonalkylated 2-iodosobenzoic acid (3, R=H).These results would indicate that microemulsions of these materials may find use in detoxification procedures.
