126267-14-9

Upstream product

• 92886-86-7 tert-butyldiphenylsilyl triflate 
• 126267-12-7 4-<(4S,5R,6R)-5-hydroxy-6-(benzoyloxymethyl)-1,3-dioxan-4-yl>-2,6-piperidinedione 
• 102487-47-8 (E,4S,5R,6R)-methyl 5,7-di(benzyloxy)-4,6-dihydroxy-2-heptenoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 591-51-5 phenyllithium 
• 20031-21-4 1,2-O-isopropylidene-α-D-xylose 
• 102487-46-7 (E)-(-)-methyl 3-<(4S,5R,6R)-5-benzyloxy-6-(benzyloxymethyl)-1,3-dioxan-4-yl>acrylate 
• 102487-45-6 (-)-4-<(4S,5R,6R)-5-hydroxy-6-(hydroxymethyl)-1,3-dioxan-4-yl>-2,6-piperidinedione 
• 92886-83-4 tert-butyltriphenylsilane 
• 98-88-4 benzoyl chloride 
• 16054-77-6 3,5-di-O-benzyl-D-xylofuranose 
• 41341-99-5 3,5-di-O-benzyl-1,2-O-isopropylidene-α-D-xylofuranose 

Downstream Products

• 126267-16-1 (1R,2S,6R,7R,9S)-(+)-9-(tert-butyldiphenylsilyloxy)-6-<(1S,2R)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 
• 126267-16-1 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-<(1R,2S)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 
• 126267-16-1 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-<(1R,2R)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 
• 126267-16-1 (1R,2S,6R,7R,9S)-9-(tert-butyldiphenylsilyloxy)-6-<(1S,2S)-1-hydroxy-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2.7>tridecan-11-one 
• 138832-14-1 (1R,2S,6R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-<(2R)-1-oxo-2-methyl-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2,7>tridecan-11-one 
• 126267-15-0 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-formyl-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2,7>tridecan-11-one 
• 85719-78-4 (+)-sesbanimide A 
• 126267-13-8 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-(hydroxymethyl)-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2,7>tridecan-11-one 

Relevant academic research and scientific papers

An alternative synthesis of (+)-sesbanimide A

D-(+)-xylose has been converted to (+)-sesbanimide A in sixteen steps.The synthetic scheme involves an ususual tricyclic silylated derivative (9a) of the monobenzoylated product of the earlier described glutarimide intermediate (7).Compound 9a is a pivotal intermediate for the construction of ring C of (+)-sesbanimide A.