1262795-58-3Relevant academic research and scientific papers
The Pd-catalyzed Alder-ene reactions of N-protected and propargylated 1-amino-2-aryl-2-cyclohexenes as a new route to C3a-arylhexahydroindoles: Towards the total synthesis of tazettine
Lehmann, Anna L.,Willis, Anthony C.,Banwell, Martin G.
, p. 1665 - 1678 (2010)
A series of N-protected and propargylated 1-amino-2-aryl-2-cyclohexenes (4) has been prepared. Several of these have been shown to undergo an intramolecular Alder-ene reaction in the presence of palladium acetate and the ligand BBEDA to afford C3a-arylhex
Synthetic studies concerning the crinine alkaloid haemultine
Gao, Nadia,Ma, Xinghua,Petit, Laurent,Schwartz, Brett D.,Banwell, Martin G.,Willis, Anthony C.,Cade, Ian A.,Rae, A. David
, p. 30 - 39 (2013/03/14)
The racemic form, (±)-1, of the structure originally assigned to the crinine alkaloid haemultine has been prepared for the first time. A key step involved the conversion of compound (±)-4 into the isomeric cis-C3a-arylhexahydroindole (±)-3 using a Pd0-cat
