1262883-59-9Relevant academic research and scientific papers
Regio- and Stereoselective Copper(II)-Catalyzed Hydrosilylation of Activated Allenes in Water: Access to Vinylsilanes
Pashikanti, Srinath,Calderone, Joseph A.,Nguyen, Matthew K.,Sibley, Christopher D.,Santos, Webster L.
, p. 2443 - 2446 (2016/06/09)
By using catalytic amounts of copper(II), 4-picoline, and dimethylphenylsilylpinacol borane, a series of allenoates were silylated on the β carbon in good to excellent yields and high (E)-selectivity. The mild and efficient silylation method is conducted in water under atmospheric conditions to afford vinylsilanes.
Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron
Thorpe, Steven B.,Guo, Xi,Santos, Webster L.
supporting information; scheme or table, p. 424 - 426 (2011/02/28)
A mild and efficient copper-catalyzed borylation of electron deficient allenoates using an sp2-sp3 mixed hybridized diboron regioselectively installs a boron moiety on the β-position with exclusive (Z)-double bond geometry.
