1262958-27-9Relevant academic research and scientific papers
Pd-Catalyzed Decarboxylative Sonogashira Reaction via Decarboxylative Bromination
Jiang, Quandi,Li, Hongyi,Zhang, Xiaofeng,Xu, Biping,Su, Weiping
, p. 2424 - 2427 (2018)
The decarboxylative alkynylation of (hetero)aryl carboxylic acids with terminal alkynes has been achieved by using a Pd(PPh3)4/PCy3 catalyst. This Pd-catalyzed method exhibits good functional group tolerance for both coupling partners and enables chemical modification of complex molecules. The establishment of this decarboxylative alkynylation reaction is attributed to the discovery of a highly selective decarboxylative bromination of (hetero)aryl carboxylic acids with NBS (N-bromosuccinimide).
First total synthesis of antrocamphin A and its analogs as anti-inflammatory and anti-platelet aggregation agents
Lee, Chia-Lin,Huang, Chi-Huan,Wang, Hui-Chun,Chuang, Da-Wei,Wu, Ming-Jung,Wang, Sheng-Yang,Hwang, Tsong-Long,Wu, Chin-Chung,Chen, Yeh-Long,Chang, Fang-Rong,Wu, Yang-Chang
supporting information; experimental part, p. 70 - 73 (2011/02/23)
Naturally occurring antrocamphin A (1) is a potent anti-inflammatory compound from the edible fungus Antrodia camphorata (Taiwanofungus camphoratus), whose wild fruiting body is used as a valuable folk medicine in Taiwan. This study is the first total syn
