1263196-68-4Relevant academic research and scientific papers
Synthesis and structural studies of organotin(IV) and organolead(IV) thiophene-2-thiocarboxylate
Singh, Suryabhan,Bhattacharya, Subrato,Noeth, Heinrich
, p. 5691 - 5699 (2011/03/17)
A few organotin(IV) ([R2SnCl2], [R3SnCl]; R = Me, Ph, nPr, or nBu) and organolead(IV) ([Ph2PbCl2], [Ph3PbCl]) compounds that contain the thiophene-2-thiocarboxylate ligand have been synthesized and characterized by 1H, 13C, 119Sn NMR; FTIR; and UV/Vis spectroscopy. The molecular structures of some of the compounds were studied by single-crystal X-ray diffraction. Structures and electronic transitions have been explained on the basis of DFT calculations. Organotin ([R2SnCl2], [R3SnCl]; R = Me, Ph, nPr, and nBu) and organolead ([Ph2PbCl2], [Ph3PbCl]) compounds that contain the thiophene-2-thiocarboxylate ligand have been synthesized and characterized by spectral and crystallographic studies. Structures and electronic transitions have been explained on the basis of DFT calculations.
