1263293-07-7Relevant academic research and scientific papers
Approach to the Core Structure of 15- epi -Exiguolide
Riefert, Alexander,Maier, Martin E.
, p. 3131 - 3145 (2018)
The synthesis of seco acid 41 of the macrolactone part of 15- epi -exiguolide, containing a bis-pyran subunit and a trans double bond, is described. Key features of the synthetic strategy include a Feringa-Minnaard asymmetric organocuprate addition to uns
Short diastereoselective synthesis of the C1-C13 (AB Spiroacetal) and C17-C28 fragments (CD spiroacetal) of spongistatin 1 and 2 through double chain-elongation reactions
Flowers, Christopher L.,Vogel, Pierre
supporting information; experimental part, p. 14074 - 14082 (2011/02/23)
A unique and practical synthetic sequence for rapid access to polyketides and to further the spiroacetals derived from them, which utilizes a bidirectional Hosomi-Sakurai allylation approach around key allylsilanes in the synthesis of the AB and CD ring s
