126330-72-1Relevant academic research and scientific papers
A Mechanistic Probe into 1,2-cis Glycoside Formation Catalyzed by Phenanthroline and Further Expansion of Scope
Li, Jiayi,Nguyen, Hien M.
supporting information, p. 4054 - 4066 (2021/07/16)
Phenanthroline, a rigid and planar compound with two fused pyridine rings, has been used as a powerful ligand for metals and a binding agent for DNA/RNA. We discovered that phenanthroline could be used as a nucleophilic catalyst to efficiently access high
Diastereoselective sp3C-O Bond Formation via Visible Light-Induced, Copper-Catalyzed Cross-Couplings of Glycosyl Bromides with Aliphatic Alcohols
Dickson, Jalen L.,Loka, Ravi S.,Luo, Long,Nguyen, Hien M.,Schaugaard, Richard N.,Schlegel, H. Bernhard,Xu, Hengfu,Yu, Fei
, p. 5990 - 6001 (2020/07/04)
Copper-catalyzed cross-coupling reactions have become one of the most powerful methods for generating carbon-heteroatom bonds, an important framework of many organic molecules. However, copper-catalyzed C(sp3)-O cross-coupling of alkyl halides with alkyl
Stereoselective synthesis of α-linked saccharides by use of per O-benzylated 2-pyridyl 1-thio hexopyranosides as glycosyl donors and methyl iodide as an activator
Mereyala,Reddy
, p. 6435 - 6448 (2007/10/02)
A new, practical, stereoselective glycosidation methodology is described where per O-benzylated 2-pyridyl 1-thio-α/β-hexopyranosyl donors of D-gluco-(1), D-galacto- (2), D-manno- (3) and L-rhamno- (4) configurations have been efficiently coupled with dive
Synthesis, NMR and Conformational Studies of some 1,4-Linked Disaccharides
Backman, Irene,Jansson, Per-Erik,Kenne, Lennart
, p. 1383 - 1388 (2007/10/02)
Synthesis of, and NMR and conformational studies on the methyl glycosides of some 1,4-linked disaccharides, containing rhamnose and fucose in the methyl glycoside residue, have been performed.The glycosylation shifts were correlated with inter-residue ato
A MILD GENERAL METHOD FOR THE SYNTHESIS OF α-LINKED DISACCHARIDES
Reddy, G. Venugopal,Kulkarni, Vinayak R.,Mereyala, Hari Babu
, p. 4283 - 4286 (2007/10/02)
Stereoselective α-glycosylations may be achieved using stable 2-pyridyl thioglycosides (anomeric mixture) having a non-participating 2-substituent as glycosyl donor and methyl iodide as an activator.
