126330-73-2Relevant academic research and scientific papers
A Glycosylation Protocol Based on Activation of Glycosyl 2-Pyridyl Sulfones with Samarium Triflate
Chang, Grace X.,Lowary, Todd L.
, p. 1505 - 1508 (2007/10/03)
(Equation Presented) Reaction of glycosyl 2-pyridyl sulfones (e.g., 2) with alcohols and samarium(III) triflate affords glycosides in moderate to excellent yields. Benzylated sulfones can be activated in preference to their benzoylated counterparts, and t
Stereoselective synthesis of α-linked saccharides by use of per O-benzylated 2-pyridyl 1-thio hexopyranosides as glycosyl donors and methyl iodide as an activator
Mereyala,Reddy
, p. 6435 - 6448 (2007/10/02)
A new, practical, stereoselective glycosidation methodology is described where per O-benzylated 2-pyridyl 1-thio-α/β-hexopyranosyl donors of D-gluco-(1), D-galacto- (2), D-manno- (3) and L-rhamno- (4) configurations have been efficiently coupled with dive
