1263324-79-3Relevant academic research and scientific papers
Simple pyrazoline and pyrazole "turn on" fluorescent sensors selective for Cd2+ and Zn2+ in MeCN
Ciupa, Alexander,Mahon, Mary F.,De Bank, Paul A.,Caggiano, Lorenzo
supporting information, p. 8753 - 8757 (2013/01/15)
An efficient two-step synthesis of pyrazoline ligand 1 is described which is an effective "turn on" fluorescent sensor for Cd2+ in MeCN. Oxidation to the corresponding pyrazole ligand 2 creates a "turn on" fluorescent sensor now selective for Zn2+ and able to distinguish it from Cd2+.
Regioselective synthesis of 1,3,5- and 1,3,4,5-substituted pyrazoles via acylation of N-Boc-N-substituted hydrazones
Tinarelli, Alessandro,Righi, Paolo,Rosini, Goffredo,Andreotti, Daniele,Profeta, Roberto,Spada, Simone
experimental part, p. 612 - 617 (2011/03/19)
Acylation of N-Boc-N-methylhydrazones followed by TFA treatment affords regioselective access to substituted pyrazoles. Both regioisomers of 1-methyl-3,5-disubstituted-1H-pyrazoles can be selectively obtained. This procedure can also be employed for the r
