1263497-44-4

Upstream product

• 1263497-43-3 (S)-methyl 4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butanoate 
• 1263497-45-5 (S)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butanal 
• 1360818-18-3 (S)-5-((tert-butyldimethylsilyl)oxy)pent-1-en-3-ol 
• 95338-04-8 (2-((S)-oxiran-2-yl)ethoxy)(tert-butyl)dimethylsilane 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 1263497-46-6 (S)-5-[(4-fluorophenoxy)methyl]-2,2,9,9,10,10-hexamethyl-3,3-diphenyl-4,8-dioxa-3,9-disilaundecane 
• 1598425-00-3 C₂₇H₄₁IO₂Si₂ 
• 1263497-45-5 (S)-4-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxy)butanal 
• 1449521-26-9 (S)-2-(tert-butyldiphenylsilyloxy)-4-oxobutyl pivalate 
• 1449521-25-8 (S)-2-(tert-butyldiphenylsilyloxy)-4-hydroxybutyl pivalate 
• 1449521-32-7 (S)-5-[(S)-1-(tert-butyldiphenylsilyloxy)tridecyl]dihydrofuran-2(3H)-one 
• 1449521-31-6 (S)-5-[(S)-1-(tert-butyldiphenylsilyloxy)tridecyl]furan-2(5H)-one 
• 1449521-30-5 (S)-tert-butyl[1-(furan-2-yl)tridecyloxy]diphenylsilane 
• 1449521-29-2 (S)-5-(tert-butyldiphenylsilyloxy)-1,1-diethoxyheptadec-2-yn-4-ol 
• 1449566-55-5 (S)-2-(tert-butyldiphenylsilyloxy)tetradecanal 
• 1449521-28-1 (S)-2-(tert-butyldiphenylsilyloxy)-1-tetradecanol 
• 1449566-54-4 (S)-2-(tert-butyldiphenylsilyloxy)tetradecyl pivalate 
• 1449566-53-3 (S)-2-(tert-butyldiphenylsilyloxy)-4-(tert-butyldimethylsilyloxy)butyl pivalate 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of Bioactive Marine Natural Product Biselyngbyolide B

A convergent strategy for the stereoselective total synthesis of biologically active marine natural product biselyngbyolide B has been developed. Key strategies of this synthesis include Jamison protocol of trans-hydroalumination/allylation for installation of C18-C23 olefin moiety and intramolecular Heck coupling for macrocyclization.

Synthesis of maresin 1 and (7S)-isomer

Maresin 1 (with the 7R carbon) and (7S)-maresin 1 were synthesized stereoselectively. The conjugated triene system was constructed by Pd-catalyzed coupling of the trans cis-dienylborane (the C10-C22 part) with the trans vinyl iodide corresponding to the C

Synthesis of enantiomerically pure 2,5-disubstituted 3-oxygenated tetrahydrofurans

The synthesis of enantiomerically pure 2,5-disubstituted 3-oxygenated tetrahydrofurans has been achieved from cheap and commercially available l-malic acid. This method was used to prepare an advanced intermediate toward CMI-977, a promising candidate for the treatment of chronic asthma. Georg Thieme Verlag Stuttgart · New York.