1263814-86-3

Basic information

• Product Name: (S)-4-benzyl-3-allyloxazolidin-2-one
• Synonyms: (S)-4-benzyl-3-allyloxazolidin-2-one
• CAS NO: 1263814-86-3
• Molecular Weight: 217.268
• Mol File: 1263814-86-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-benzyl-3-allyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-benzyl-3-allyloxazolidin-2-one(1263814-86-3)
• EPA Substance Registry System: (S)-4-benzyl-3-allyloxazolidin-2-one(1263814-86-3)

Safety Data

• Hazardous Substances Data: 1263814-86-3(Hazardous Substances Data)

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 106-95-6 allyl bromide 

Downstream Products

• 1287665-52-4 C₆₃H₈₇N₉O₆ 
• 1207868-49-2 C₆₃H₈₇N₉O₆ 
• 1287665-51-3 C₃₂H₄₄N₄O₄ 
• 1207868-48-1 C₃₂H₄₄N₄O₄ 

Relevant articles and documents

A General Approach to Intermolecular Olefin Hydroacylation through Light-Induced HAT Initiation: An Efficient Synthesis of Long-Chain Aliphatic Ketones and Functionalized Fatty Acids

Herein, an operationally simple, environmentally benign and effective method for intermolecular radical hydroacylation of unactivated substrates by employing photo-induced hydrogen atom transfer (HAT) initiation is described. The use of commercially available and inexpensive photoinitiators (Ph2CO and NHPI) makes the process attractive. The olefin hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.