126385-38-4Relevant academic research and scientific papers
Abnormal Nucleophilic Substitution on Methoxytropone Derivatives: Steric Strategy to Synthesize 5-Substituted Azulenes
Kumar, Neha Rani,Agrawal, Abhijeet R.,Zade, Sanjio S.
supporting information, p. 14064 - 14071 (2019/11/03)
Azulene is a non-alternant non-benzenoid aromatic system, and in turn, it possesses unusual photophysical properties. Azulene-based conjugated systems have received increasing interest in recent years as optoelectronic materials. Despite the routes availa
A THERMALLY-INDUCED RADICAL REARRANGEMENT OF 2-ARYLMETHOXYTROPONES TO 3- AND 5-ARYLMETHYLTROPOLONES
Takeshita, Hitoshi,Mametsuka, Hiroaki,Chisaka, Atsuko,Matsuo, Norihide
, p. 73 - 76 (2007/10/02)
2-Arylmethoxytropones, i.e., 2-benzyloxytropone, 2-(p-tolylmethoxy)tropone, 2-(4-bromophenylmethoxy)tropone, 2-(4-chlorophenylmethoxy)tropone, 2-(4-methoxyphenylmethoxy)tropone, and 2-(1-naphthylmethoxy)tropone, rearranged upon heating to the 3- and 5-arylmethyltropolones via the radical intermediates.Similarly, 5-bromo-2-(p-tolylmethoxy)tropone gave 5-bromo-3-(p-tolylmethyl)tropolone.
