126435-89-0

Upstream product

• 64-19-7 acetic acid 
• 75553-23-0 (E)-5-phenyl-2-penten-1-ol 
• 108-24-7 acetic anhydride 
• 104-53-0 3-phenyl-propionaldehyde 
• 590-97-6 acetoxymethyl bromide 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 

Downstream Products

• 344360-07-2 dimethyl 3-(2-phenylethyl)-2-propenylmalonate 
• 945428-61-5 (E)-1-benzyloxy-5-phenylpent-2-ene 
• 147330-82-3 (E)-5-phenyl-1-triethylgermyl-2-pentane 
• 1000376-25-9 (S)-4,4,5,5-tetramethyl-2-[5-phenyl-1-penten-3-yl]-1,3,2-dioxaborolane 
• 1000376-26-0 (3R)-3-(4',4',5',5'-tetramethyl-1',3',2’-dioxaborolanyl)-5-phenylpent-1-ene 
• 1607805-12-8 C₁₃H₁₄F₂ 
• 1607805-00-4 (3-allyl-4,4-difluorohex-5-en-1-yl)benzene 
• 1607805-34-4 C₁₂H₁₄F₂O 

Relevant academic research and scientific papers

Enantioselective C-C Bond Formation during the Oxidation of 5-Phenylpent-2-enyl Carboxylates with Hypervalent Iodine(III)

The oxidation of (5-acyloxypent-3-enyl)benzene with hypervalent iodine(III) afforded 2-oxy-1-(oxymethyl)tetrahydronaphthalene under metal-free conditions. The acyloxy group may nucleophilically participate in the oxidative cyclization. A lactate-based chi

Disubstituted Z-allylic esters by Wittig-Schlosser reaction using methylenetriphenylphosphorane

β-Lithiooxyphosphonium ylides, generated in situ from aldehydes and methylenetriphenylphosphorane, react with halomethyl esters to form disubstituted allylic esters in good yields and with high Z-selectivity.

Iridium-catalysed allylic substitution: Stereochemical aspects and isolation of IrIII complexes related to the catalytic cycle

Ir-catalysed allylic alkylations of enantiomerically enriched monosubstituted allylic acetates proceed with up to 87% retention of configuration using P(OPh)3 as ligand. High retention enantioselectivity of up to 86% ee in asymmetric allylic alkylations of achiral or racemic substrates is achieved with monodentate phosphorus amidites as ligands. Lithium N-tosylbenzylamide was identified as a suitable nucleophile for allylic aminations. Of particular importance is the use of lithium chloride as an additive, generally leading to increased enantioselectivities. Two (π-allyl)IrIII complexes were characterised by X-ray crystal structure analysis and spectroscopic data.

Stereoselectivity and regioselectivity in the segment-coupling prins cyclization

The scope of the segment-coupling Prins cyclization has been investigated. The method is outlined in Scheme 1 and involves esterification of a homoallylic alcohol.(1), reductive acetylation to give the α-acetoxy ether (3), and cyclization on treatment wit

Allyl- and propargylchromium reagents generated by a chromium(III) ate-type reagent as a reductant and their reactions with electrophiles

A chromium ate-type reagent 'Bu5CrLi2' reacts with allylic and propargylic phosphates to generate the corresponding allyl- and propargylchromium (propargyl = prop-2-ynyl) reagents which further react with a variety of electrophiles such as aldehydes, ketones, imines, and isocyanates to afford the corresponding adducts in high yields.