126452-06-0Relevant academic research and scientific papers
Chiral environment of catalytic sites in the chiral metal-organic frameworks
Lee, Misun,Shin, Sung Min,Jeong, Nakcheol,Thallapally, Praveen K.
, p. 9349 - 9352 (2015)
Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place
Pyrophosphoric acid ester compound, bisphosphate ester compound and catalyst
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Paragraph 0057; 0060; 0061, (2017/09/20)
The invention pertains to a novel pyrophosphoric acid ester compound represented by formula (1) and a bisphosphoric acid ester compound represented by formula (2). In the formulas, R is an aryl group, organic silyl group, or halogen atom. These compounds can adequately activate carbonyl compounds, imine compounds, and the like due to having higher acidity than conventional phosphoric acid ester compounds. Usefulness as a metal ligand is also expected.
Cationic Chiral Fluorinated Oxazaborolidines. More Potent, Second-Generation Catalysts for Highly Enantioselective Cycloaddition Reactions
Mahender Reddy, Karla,Bhimireddy, Eswar,Thirupathi, Barla,Breitler, Simon,Yu, Shunming,Corey
supporting information, p. 2443 - 2453 (2016/03/08)
The coordination of chiral ligands to Lewis acid metal derivatives, a useful strategy for enantioselective, electrophilic catalysis, generally leads to a lower level of catalytic activity than that of the original uncomplexed compound. Activation by furth
MANUFACTURING METHOD OF OPTICAL ACTIVE ALCOHOL
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Paragraph 0117, (2017/05/04)
PROBLEM TO BE SOLVED: To provide a method for providing optical active alcohol capable of being a perfume material or a cold sensation raw material with high optical purity and high selectivity by conducting an asymmetric carbonyl-en ring closure reaction
