126456-15-3Relevant academic research and scientific papers
COMPLEXES OF CYCLOMALTOHEPTAOSE WITH AROMATIC DIAZO COMPOUNDS: FORMATION AND REACTIONS
Abelt, Christopher J.,Lokey, Jonathan S.,Smith, Shelley H.
, p. 119 - 130 (1989)
Pyrolysis of the relatively stable, solid complexes of cyclomaltoheptaose (β-cyclodextrin) with phenyldiazomethane, 1-diazo-1-phenylethane, and diazo(diphenyl)methane results in degradation of the labile guests.The host matrix exerts "reaction-vessel" and "shape-selectivity" effects upon the reaction pathways of the guests and derivatives.The carbene insertion reaction with the β-cyclodextrin hydroxyl groups is regioselective.
