Carbohydrate Research p. 119 - 130 (1989)
Update date:2022-09-26
Topics:
Abelt, Christopher J.
Lokey, Jonathan S.
Smith, Shelley H.
Pyrolysis of the relatively stable, solid complexes of cyclomaltoheptaose (β-cyclodextrin) with phenyldiazomethane, 1-diazo-1-phenylethane, and diazo(diphenyl)methane results in degradation of the labile guests.The host matrix exerts "reaction-vessel" and "shape-selectivity" effects upon the reaction pathways of the guests and derivatives.The carbene insertion reaction with the β-cyclodextrin hydroxyl groups is regioselective.
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