1264737-57-6

Basic information

• Product Name: N-benzoyl-4-methylphenyl sulfonimidoyl fluoride
• Synonyms: N-benzoyl-4-methylphenyl sulfonimidoyl fluoride
• CAS NO: 1264737-57-6
• Molecular Weight: 277.319
• Mol File: 1264737-57-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-benzoyl-4-methylphenyl sulfonimidoyl fluoride(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoyl-4-methylphenyl sulfonimidoyl fluoride(1264737-57-6)
• EPA Substance Registry System: N-benzoyl-4-methylphenyl sulfonimidoyl fluoride(1264737-57-6)

Safety Data

• Hazardous Substances Data: 1264737-57-6(Hazardous Substances Data)

Upstream product

• 93-97-0 benzoic acid anhydride 
• 667-14-1 N-benzoyl-p-toluene sulfonimidoyl chloride 
• 18513-02-5 N-(4-tolylsulfinyl)-benzamide 
• 6873-55-8 p-tolylsulfinyl amide 

Downstream Products

• 1264737-70-3 N-[oxo(p-tolyl)(trifluoromethyl)-λ6-sulfanylidene]benzamide 
• 107046-12-8 4-nitrophenyl N-benzoyl-p-tolueneiminosulfonate 

Relevant articles and documents

Silicon-Free SuFEx Reactions of Sulfonimidoyl Fluorides: Scope, Enantioselectivity, and Mechanism

SuFEx reactions, in which an S?F moiety reacts with a silyl-protected phenol, have been developed as powerful click reactions. In the current paper we open up the potential of SuFEx reactions as enantioselective reactions, analyze the role of Si and outline the mechanism of this reaction. As a result, fast, high-yielding, “Si-free” and enantiospecific SuFEx reactions of sulfonimidoyl fluorides have been developed, and their mechanism shown, by both experimental and theoretical methods, to yield chiral products.