18513-02-5

Basic information

• Product Name: N-(4-tolylsulfinyl)-benzamide
• Synonyms: N-(4-tolylsulfinyl)-benzamide
• CAS NO: 18513-02-5
• Molecular Weight: 259.329
• Mol File: 18513-02-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(4-tolylsulfinyl)-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-tolylsulfinyl)-benzamide(18513-02-5)
• EPA Substance Registry System: N-(4-tolylsulfinyl)-benzamide(18513-02-5)

Safety Data

• Hazardous Substances Data: 18513-02-5(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 6873-55-8 p-tolylsulfinyl amide 
• 108-88-3 toluene 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 667-14-1 N-benzoyl-p-toluene sulfonimidoyl chloride 
• 107046-12-8 4-nitrophenyl N-benzoyl-p-tolueneiminosulfonate 

Relevant articles and documents

Palladium-Catalyzed Carbonylation of Aryl Iodides with Sulfinamides

A facile palladium(0)-catalyzed carbonylative protocol for the generation of new acyl-sulfinamides in moderate to good yields is described. Aliphatic and aromatic sulfinamides were exploited as hitherto unexplored nucleophiles in carbonylation chemistry,

Synthesis of CF3-substituted sulfoximines from sulfonimidoyl fluorides

N-Protected trifluoromethyl-substituted sulfoximines have been prepared by treatment of sulfonimidoyl fluorides with a combination of the Ruppert-Prakash reagent (TMSCF3) and tetrabutyl ammonium fluoride (TBAF). The starting materials were accessed following two synthetic routes, and for each reaction sequence the substrate scope was evaluated. Accordingly, a wide variety of aryl-substituted products were obtained in moderate to good yield.