126488-91-3Relevant academic research and scientific papers
Reaction of Trifluoromethanesulphonyl Chloride with Alkenes catalysed by a Ruthenium(II) Complex
Kamigata, Nobumasa,Fukushima, Takamasa,Yoshida, Masato
, p. 1559 - 1560 (1989)
The raction of trifluoromethanesulphonyl chloride with alkenes in the presence of dichlorotris(triphenylphosphine)ruthenium(II) gives 1:1 adducts with extrusion of sulphur dioxide.
TfNHNHBoc as a Trifluoromethylating Agent for Vicinal Difunctionalization of Terminal Alkenes
Guo, Jing-Yu,Wu, Ruo-Xin,Jin, Ji-Kang,Tian, Shi-Kai
, p. 3850 - 3853 (2016)
An unprecedented application of trifluoromethanesulfonyl hydrazides as trifluoromethylating agents has been demonstrated in two vicinal difunctionalization reactions of terminal alkenes: the copper-catalyzed three-component vicinal chlorotrifluoromethylat
Cu Photoredox Catalysts Supported by a 4,6-Disubstituted 2,2′-Bipyridine Ligand: Application in Chlorotrifluoromethylation of Alkenes
Alkan-Zambada, Murat,Hu, Xile
supporting information, p. 3928 - 3935 (2018/10/24)
Interest in base metal catalysis motivates the development of Cu-based photoredox catalysts for organic synthesis. However, only a few Cu catalysts have been applied in photoredox reactions, the majority of which contain one or two 1,10-phenanthroline lig
Cu-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl
Zhang, Wei,Lin, Jin-Hong,Xiao, Ji-Chang
, p. 25 - 31 (2018/09/18)
Although CF3SO2Cl is an efficient chlorotrifluoromethylation reagent, an expensive transition metal complex usually has to be used. We found that CuCl2-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl occurred smoothly under mild conditions. A wide substrate scope and good functional group compatibility were observed.
Iron-Mediated Chlorotrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate
Yang, Bin,Xu, Xiu-Hua,Qing, Feng-Ling
, p. 465 - 468 (2016/06/01)
An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride (FeCl3) as the Cl source and the Langlois reagent (CF3SO2Na)
Fluoroalkyl derivative and process for preparing the same
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, (2008/06/13)
Fluoroalkyl derivatives which are novel compounds represented by the following general formula (I) or (II) of: STR1 or (wherein R1 stands for STR2 (where X stands for a hydrogen atom, a chlorine atom, a bromine atom, a fluorine atom, an iodine
Novel Perfluoroalkylation of Alkenes with Perfluoroalkanesulphonyl Chlorides Catalysed by a Ruthenium(II) Complex
Kamigata, Nobumasa,Fukushima, Takamasa,Terakawa, Yoshie,Yoshida, Masato,Sawada, Hideo
, p. 627 - 633 (2007/10/02)
The perfluoroalkylation of acyclic and cyclic alkenes by perfluoroalkanesulphonyl chlorides 1 has been investigated in the presence of a ruthenium(II) catalyst.The addition reactions proceeded smoothly, with extrusion of sulphur dioxide, in alkenes posses
